Instrument online · Holder #24 reserved

The 400 MHz NMR facility at BCE

Bruker Ascend Evo · Aarhus University · Open to all AU researchers. Submit samples, access data, and get certified — all in one place.

RF excitation · 90° pulse
9.4TMagnetic field
400MHzProton frequency
BB/H/DSmartProbe
24Sample positions
24/7Automated access
The instrument

What you're working with

A research-grade 400 MHz Bruker Ascend Evo with automated sample handling — available to all AU researchers around the clock.

The facility runs a 9.4 Tesla superconducting magnet with a SmartProbe capable of detecting all common NMR-active nuclei (¹H, ¹³C, ¹⁵N, ¹⁹F, ³¹P and more) without probe swaps. A 24-position automated sample changer enables unattended overnight experiments.

Data is delivered automatically by email within 1–2 minutes of experiment completion, backed up to Proton Drive, and available for download via a direct link.

¹H / ¹³C / ¹⁵N ¹⁹F / ³¹P 24-position changer Night queue automation Auto data email Proton Drive backup
Magnet9.4 T superconducting, actively shielded
Frequency400 MHz (¹H)
ProbeSmartProbe BB/H/D · auto tune & match
ChangerSampleXpress 24 · auto load, eject, shim
StabilityCryo-cooled, near-zero field drift
OperationUnattended nights & weekends
Submit a sample · 1 of 2

Five rules. Zero exceptions.

Every failed experiment at BCE NMR traces back to one of these five preparation steps. Get them right every time.

RULE 01Tube spec

178 × 5 mm tube

No other dimensions. Wrong tube size prevents proper shimming in the SampleXpress changer and produces broad, unusable peaks.

RULE 02Solvent lock

Deuterated solvent only

CDCl₃, DMSO-d₆, D₂O, CD₃OD. Non-deuterated solvents produce a massive peak that swamps your compound signal completely.

RULE 03Volume

600 µL exactly

Fills the active coil of the SmartProbe. Too little loses sensitivity; too much makes shimming impossible. Aim for ≈ 4 cm column height.

RULE 04Clarity

No particles

Centrifuge or filter before submission. Suspended solids disrupt field homogeneity, broaden every peak, and ruin the baseline.

RULE 05Labelling

Label: name · ID · solvent

Unlabelled tubes are removed from the changer without running. Include your name, a compound identifier or date, and the solvent used.

Submit a sample · 2 of 2

Day queue vs night queue

Know which queue to use before you walk to the lab. The rules exist to keep the changer fair for everyone.

Day queue
08:00 – 18:00

For experiments under 35 minutes. First come, first served.

Place your sample any time during working hours and it runs in order.

⚠ Holder #24 is permanently reserved for the weekly calibration reference. Never use it.
Night queue
18:00 – 08:00

For experiments 35 minutes or longer. Weekends included.

Place samples only after 15:00 — earlier placement blocks the day changer unnecessarily.

Collect within 1–48 hours of completion. You receive an automatic email when done.

ExperimentScansTimeQueue
¹H NMR (quick)4–16~1.5 minDay
¹H NMR (high res)64–128~5–10 minDay
¹³C NMR (quick)32–128~8–15 minDay
¹³C NMR (routine)256–512~20–30 minNight
HSQC / COSY4–16~15–30 minNight
¹³C NMR (high res)1024~60 minNight
HMBC / DOSY8–32~30–120 minNight
Experiments

Find the right experiment

Search by name, nucleus, or technique. Click any card for sample requirements, scan counts, and tips.

¹H NMR · Proton

Sample: ≥ 5 mg

  • Quick: 4 scans (~1.5 min)
  • High res: 16–64 scans
Always run ¹H first. TMS reference at 0 ppm. Check solvent residual peak positions.
¹³C NMR · Carbon backbone

Sample: ≥ 50 mg (1% natural abundance)

  • Quick: 32 scans (~8 min, day)
  • Routine: 256 scans
  • High res: 512 scans (~30 min, night)
  • Ultra: 1024 scans (~60 min, night)
SNR ∝ √scans. Doubling SNR needs 4× more scans — increasing concentration is far more efficient.
HSQC · ¹H–¹³C one-bond

Sample: 50–100 mg

  • Fast: 4 scans
  • Detailed: 16 scans (~30 min, night)
Shows which proton is directly bonded to which carbon. Essential for complete assignment.
COSY · ¹H–¹H coupling

Sample: 5–10 mg

  • Screen: 2 scans
  • Detailed: 16 scans (~30 min, night)
Maps ¹H spin systems via 3-bond coupling. Identify proton neighbours across the molecule.
HMBC · Long-range ¹H–¹³C

Sample: 50–100 mg

  • Standard: 8 scans
  • Extended: 16 scans
2–4 bond H–C correlations. Key for quaternary carbons and completing the carbon skeleton.
¹⁹F NMR · Fluorine

Sample: 5–10 mg (very sensitive)

  • Quick: 16 scans
  • Detailed: 64 scans
100% natural abundance and highly sensitive — excellent for trace detection and fluorinated drug analysis.
³¹P NMR · Phosphorus

Sample: 5–10 mg

  • Screen: 16 scans (~1 min, day)
  • Detailed: 64 scans
100% abundance. Wide chemical shift range (−200 to +250 ppm). Fast and informative.
DEPT · Multiplicity editing

Sample: ≥ 20 mg

  • DEPT-45: CH, CH₂, CH₃ all positive
  • DEPT-90: CH only
  • DEPT-135: CH and CH₃ up, CH₂ down
Combine DEPT-135 with ¹³C to identify quaternary carbons (absent in DEPT spectrum).
Water suppression · Presat

Sample: Aqueous, ~10 mg

  • 16–64 scans
2 s presaturation at the water frequency. Flattens baseline and reveals signals near 4.8 ppm.
HSQC-TOCSY · Spin system tracing

Sample: 50–100 mg

  • Standard: 8 scans
  • Enhanced: 32 scans
Traces full ¹H spin networks displayed on the ¹³C axis. Powerful for carbohydrate and ionic liquid assignment.
DOSY · Diffusion-ordered

Sample: ~10 mg

  • 32–64 scans per gradient step
Separates components by diffusion coefficient. Ideal for complex mixtures without physical separation.
PS ROESY · Spatial proximity

Sample: ~10 mg

  • 16–64 scans
200 ms mixing time is a good start. Shows through-space ¹H–¹H correlations for conformational analysis.
¹⁵N NMR · Nitrogen

Sample: ≥ 50 mg, or ¹⁵N-labelled material

  • 128–512 scans
Very low natural abundance (0.37%). Isotope labelling strongly preferred. Use broadband decoupling.
Solvents

Solvent selection guide

Residual ¹H and ¹³C shifts, polarity, and common use cases. Click any card for details.

CDCl₃ · Non-polar

Best for organic compounds, lipids, non-polar molecules.

¹H: 7.26 ppm · ¹³C: 77.16 ppm (triplet)

Default first choice. Avoid with highly polar or ionic samples. Add TMS for ¹H referencing.
DMSO-d₆ · Polar aprotic

Best for sugars, ionic liquids, polar organics, cellulose.

¹H: 2.50 ppm · ¹³C: 39.52 ppm (septet)

Viscous and hygroscopic — work quickly after opening. N–H and O–H protons visible.
CD₃OD · Polar protic

Best for biomolecules, natural products, amino acids.

¹H: 3.31 ppm · ¹³C: 49.00 ppm

Exchangeable O–H and N–H protons disappear by deuterium exchange — plan accordingly.
D₂O · Water-soluble

Best for proteins, carbohydrates, water-soluble analytes.

¹H residual: 4.79 ppm (H₂O)

All exchangeable protons vanish. Use water presaturation to suppress residual H₂O peak.
Acetone-d₆ · Polar aprotic

Best for ketones, esters, moderately polar compounds.

¹H: 2.05 ppm · ¹³C: 29.84 ppm

Good alternative to DMSO when lower viscosity is needed. Volatile — cap promptly.
TFA-d · Very acidic

Best for basic heterocycles, alkaloids.

¹H: 11–12 ppm · ¹³C: 116.6 ppm

Very strong acid — protonates basic nitrogen compounds. Use only when necessary.
Pyridine-d₅ · Basic

Best for coordination complexes, acid-sensitive samples.

¹H: 8.74 ppm · ¹³C: 150.3 ppm

Highly basic solvent. Useful for samples that precipitate in neutral solvents.
THF-d₈ · Medium polar

Best for organometallics, air-sensitive samples.

¹H: 1.72 ppm · ¹³C: 67.57 ppm

Handle under inert atmosphere for air-sensitive materials. Good for organometallics.
Benzene-d₆ · Aromatic

Best for hydrocarbons, non-polar organometallics.

¹H: 7.16 ppm · ¹³C: 128.4 ppm

⚠ Toxic — fume hood only. Consider toluene-d₈ as a safer alternative.
Toluene-d₈ · Aromatic

Best for hydrophobic samples, non-polar polymers.

¹H: 2.09 ppm · ¹³C: 20.4 ppm

Often a safer choice than benzene-d₆ with similar dissolving power for non-polar compounds.
Online certification · Required for all new users
Get certified before you touch the instrument

Five modules with inline diagrams, an interactive sample preparation simulation, and a 10-question final assessment. Pass at 90% to receive a printable certificate — issued instantly, no waiting.

~35 minutes 90% pass mark Instant certificate Any device Unlimited retries
Start training now
Module 1 — How NMR works
Module 2 — Lab rules & queues
Module 3 — Sample preparation sim
Module 4 — Experiments & solvents
Module 5 — Data & software
Final assessment · 10 questions
Pass at 90% → certificate emailed to lab manager → TopSpin username created
Data access

Your data, delivered automatically

After your experiment completes, data arrives by email within minutes — with a Proton Drive backup for a limited period.

Experiment runsAutomated queue
Email in ~2 mindata@bcenmr.dk
Download dataDirect link
Save local copy48 hr retention

Add data@bcenmr.dk to your safe senders. Data is backed up to Proton Drive for a limited period — always keep your own copy.

MN

MestreNova license

AU license on the iNANO website. Requires AU network or VPN. Recommended for beginners — download and install before your first run.

TS

TopSpin license

Free academic license from bruker.com. Best for advanced processing and viewing raw FID data. Both open Bruker format natively.

FAQ

Quick answers

The questions every new user asks — answered directly.

How do I get my data after an experiment?

Within 1–2 minutes of completion, an automatic email from data@bcenmr.dk arrives with a download link. Add this address to your safe senders. Data is also backed up to Proton Drive for a limited period — always keep your own copy.

Which software do I use to process my data?

MestreNova (recommended for beginners): download from mestrelab.com; the AU license is on the iNANO website (requires AU network or VPN). TopSpin: free academic license at bruker.com; better for advanced processing and viewing raw FIDs. Both open Bruker format natively.

When can I place a night queue sample?

Night queue samples must be placed after 15:00 only. Earlier placement occupies the changer unnecessarily during day-queue hours. Collect within 1–48 hours of completion.

Can I book the instrument for a specific time?

The queue system is first-come first-served and runs automatically — there is no booking system. Day queue samples run when the changer reaches them. Night queue samples run unattended overnight. For unusual experiments or very long runs, contact Axel first.

Why does ¹³C need so much more sample than ¹H?

¹³C has only 1% natural abundance vs 99.9% for ¹H. Far fewer nuclei are detectable per milligram. SNR scales with √(scans) — doubling SNR requires 4× more scans. Increasing concentration is almost always more efficient.

What is holder #24?

Holder #24 permanently contains the weekly magnet calibration reference sample. It is always reserved and must never be used for submitted samples under any circumstances.

My spectrum looks terrible — broad peaks, poor baseline. Why?

The most common causes: (1) particles or undissolved material — centrifuge or filter; (2) wrong tube size — must be 178 × 5 mm; (3) insufficient sample volume — must be 600 µL; (4) non-deuterated solvent used. Run through the prep checklist before resubmitting.

Which experiments need TopSpin username access?

All experiments submitted through the automated queue require a registered TopSpin username. This is created by Axel after you pass the induction course. The certification email notifies him automatically.

Contact

Get in touch

Questions about sample preparation, experiments, software, or access — Axel is glad to help.

Axel Rosenvinge
Axel Rosenvinge NMR Lab Manager · BCE, Aarhus University axelro@bce.au.dk
NMR Support
NMR Facility Support General enquiries, booking, troubleshooting nmr@bce.au.dk
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Location

Department of Biological and Chemical Engineering
Aarhus University, Gustav Wieds Vej 10, 8000 Aarhus C

Access hours

Automated queue runs 24/7. For in-person instrument access or training, contact Axel to arrange access.

🎓

New user onboarding

Complete the online induction course, then email Axel with your certificate. TopSpin username will be created within 1–2 working days.